m-Xylene

CAS Number: 108-38-3
Chemical Formula: C8H10
Synonyms: m-Xylene, 2,4-Xylene, 3-methyltoluene
Appearance: Colorless liquid
HS Code: 29024200
MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Description

Xylene has three isomers: ortho‑xylene, meta‑xylene and para‑xylene. Commercial xylene is usually a blend of these three isomers and may also include ethylbenzene, along with small quantities of toluene, trimethylbenzene, phenol, thiophene, pyridine and other non‑aromatic hydrocarbons. Among them, meta‑xylene is the main component in commercial xylene. Physical properties of the three isomers are shown below:

Isomer Melting Point (℃) Boiling Point (℃) Flash Point (℃) Lower Expl. (%) Upper Expl. (%) Auto Temp. (℃)
ortho- -25 144 32 0.9 6.7 463
meta- -48 139 27 1.1 7.0 527
para- 13 138 27 1.1 7.0 528  

m-Xylene

Parameters

Parameter Value
Melting point -48 °C (lit.)
Boiling point 138-139 °C (lit.)
density 0.868 g/mL at 25 °C (lit.)
vapor density 3.7 (vs air)
vapor pressure 16 mm Hg (37.7 °C)
refractive index n 20/D 1.497 (lit.)
Fp 77 °F
storage temp. 2-8°C
solubility Miscible with many organic solvents, including alcohol and ether
form Liquid
pka >15 (Christensen et al., 1975)
color Colorless
Odor Like benzene; characteristic aromatic.
Odor Threshold 0.041 ppm
explosive limit 1.1-7% (V)
Water Solubility Miscible with organic solvents. Immiscible with water.
Merck 14,10081
BRN 605441
Henry’s Law Constant 14.80 at 45.00 °C; 17.26 at 50.00 °C; 19.90 at 55.00 °C; 23.01 at 60.00 °C; 27.46 at 70.00 °C (static headspace-GC, Park et al., 2004)
Dielectric constant 2.4
Exposure limits NIOSH REL: 100 ppm (435 mg/m³), STEL 150 ppm (655 mg/m³), IDLH 900 ppm; OSHA PEL: TWA 100 ppm; ACGIH TLV: TWA 100 ppm, STEL 150 ppm
InChIKey IVSZLXZYQVIEFR-UHFFFAOYSA-N
LogP 3.16 at 20℃
Surface tension 28.47 mN/m at 298.15 K
CAS DataBase Reference 108-38-3 (CAS DataBase Reference)
NIST Chemistry Reference Benzene, 1,3-dimethyl- (108-38-3)
EPA Substance Registry System m-Xylene (108-38-3)

Safety Information

Item Value
Hazard Codes Xn, T, F
Risk Statements 10-20/21-38-39/23/24/25-23/24/25-11-36/38
Safety Statements 25-45-36/37-16-7
RIDADR UN 1307 3/PG 3
OEB A
OEL TWA: 100 ppm (435 mg/m³), STEL: 150 ppm (655 mg/m³)
WGK Germany 2
RTECS ZE2275000
Autoignition Temperature 982 °F
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29024200
Hazardous Substances Data 108-38-3 (Hazardous Substances Data)
Toxicity LD50 orally in rats: 7.71 ml/kg (Smyth)

Product Application of m-Xylene CAS# 108-38-3

Meta-xylene is mainly used as a solvent for manufacturing isophthalic acid, which is further processed into unsaturated polyester resins and coatings. It is also used to synthesize meta-toluic acid, isophthalic acid nitrile, pharmaceutical ingredients such as lidocaine and oxymetazoline, as well as other fine chemicals. In addition, it serves as a raw material for flavors, dye intermediates, and oil-soluble colorants for color films.
Fast delivery time
Inventory: 2–3 working days; New production: 7–10 working days

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